some small typos in 5

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Valentin Boettcher 2022-09-29 13:38:45 +02:00
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@ -39,12 +39,14 @@ In thermodynamics the second law tells us that in this setting no
energy can be extracted indefinitely in a periodic manner. It turns
out, that in the full quantum case such a result can be obtained by
studying bounds on the ergotropy of the system as is done in
\cref{sec:ergo_general}. Remarkably these bounds will turn out to be
finite. We will review a general bound for single bath systems in
\cref{sec:ergo_general}. Remarkably, these bounds, originating from
\refcite{Biswas2022May,Alicki2013Apr,Lobejko2021Feb}, will turn out to
be finite for finite dimensional systems coupled to infinite baths. We
will review a general bound for single bath systems in
\cref{sec:ergoonebath} and study an explicit calculation for a simple
case in \cref{sec:explicitergo}. The
explicit ergotropy calculation will elucidate under which conditions
the bound of \cref{sec:ergoonebath} may be expected to be tight.
case in \cref{sec:explicitergo}. The explicit ergotropy calculation
will elucidate under which conditions the bound of
\cref{sec:ergoonebath} may be expected to be tight.
The second problem is a generalization of the above considerations to
systems coupled to multiple baths of different temperature. In this
@ -91,9 +93,10 @@ as~\cite{Binder2018}
\end{equation}
which is the maximal energy that can be extracted from a system
through cyclic modulation of the Hamiltonian \(H\). A state is called
passive iff the maximizing \(U\) \cref{eq:ergo_def} is the identity
passive iff the maximizing \(U\) in \cref{eq:ergo_def} is the identity
\(\id\). In other words, a state is passive if its energy can not be
reduced through unitary transformations and its ergotropy vanishes.
reduced through unitary transformations and thus its ergotropy
vanishes.
In \refcite{Niedenzu2018Jan} the ergotropy of the system is employed
for the definition of heat to derive a tighter second law. The
@ -110,9 +113,9 @@ condition~\cite{Lenard1978Dec}
\end{equation}
where \(n<∞\) is the Hilbert space dimension. This condition is both
necessary and sufficient. Examples of passive states are the state of
the micro-canonical ensemble or Gibbs states. Gibbs states are further
distinguished by additional features described
in \refcite{Lenard1978Dec}, which can be connected to formulations of the
the micro-canonical ensemble and also Gibbs states. Gibbs states are
further distinguished by additional features described in
\refcite{Lenard1978Dec}, which can be connected to formulations of the
zeroth and second laws of thermodynamics.
One of these properties is complete passivity. Completely passive
@ -156,7 +159,8 @@ appropriate. KMS states only enter the NMQSD/HOPS formalism
indirectly, as they predict the expression for the spectral density of
the finite temperature noise in \cref{sec:lin_finite}. Due to the
formulation of the NMQSD which only relies on bath correlation
functions, the problem of non-existing states is circumvented.
functions, the problem of formally non-existing states is
circumvented.
In fact, we see in \cref{fig:bcf_approx} that the BCF of an infinite
bath can be approximated very well by a finite number of evenly spaced
@ -207,7 +211,7 @@ finite. This amounts to the formulation of the second law: ``No energy
may be extracted from a single bath in a cyclical manner''. For
systems obeying weak coupling dynamics, thermodynamic laws can be
derived in certain situations\footnote{very slow or very fast
modulation of the system hamiltonian}\cite{Binder2018}, which imply
modulation of the system hamiltonian}~\cite{Binder2018}, which imply
the answer ``yes'' for the above questions. In the non-Markovian case
however, those arguments do not hold anymore.
@ -215,16 +219,17 @@ For finite dimensional baths, we always have finite ergotropies, as
their Hamiltonians are bounded. In the infinite dimensional case, we
may expect that the ergotropy is still finite for some models, as long
as the energies of the thermal states for those models is finite. This
assumption breaks down when we consider infinite baths, whose thermal
energy is unbounded even for finite temperatures. We therefore
slightly reformulate our problem. The question is now, whether the
ergotropy can be made arbitrarily large by enlarging the bath. This is
consistent with approaching the infinite bath case as a limit.
assumption breaks down when we consider baths consisting of an
infinite number of subsystems, whose thermal energy is unbounded even
for finite temperatures. We therefore slightly reformulate our
problem. The question is now, whether the ergotropy can be made
arbitrarily large by enlarging the bath. This is consistent with
approaching the infinite bath case as a limit.
There is a simple and general argument that provides an upper bound on
the ergotropy of states of the form~\cref{eq:simple_initial_state}
based on the special form of Gibbs states and relative entropy. The
latter quantity allows the application of quantum informational tools,
latter quantity allows the application of quantum informational tools
even in the presence of infinite baths if we are careful in taking
limits.
@ -677,8 +682,8 @@ energy that can be extracted out of the system in relation to the
energy that is simply transferred between the baths.
An argument based on entropy may be made for the periodic steady state
as was shown in \refcite{Kato2016Dec} and is reproduced here with the
slight generalization of multiple baths and modulated coupling. We
as was shown in \refcite{Kato2016Dec} and is reproduced here with a
slight generalization to multiple baths and modulated coupling. We
will find a Clausius-like form of the second law. The left-hand side
of this inequality can then be interpreted as thermodynamic cost of
the cyclical process.
@ -790,11 +795,11 @@ motivated in \refcite{Riechers2021Apr}, where heat is identified with
bath is being considered and brought into connection with
information-theoretic quantities.
If one defines heat in this
way~\cite{Kato2016Dec,Riechers2021Apr,Strasberg2021Aug},
If one defines heat in this way as is done in
\refcite{Kato2016Dec,Riechers2021Apr,Strasberg2021Aug},
\cref{eq:secondlaw_cyclic} amounts to the Clausius inequality. The
definition of heat as bath energy change is corroborated
in \refcite{Esposito2015Dec} where it is shown, ableit for fermionic
definition of heat as bath energy change is corroborated in
\refcite{Esposito2015Dec} where it is shown, ableit for fermionic
baths, that a definition of heat involving any nonzero fraction of the
interaction energy will lead to the internal energy (as defined by the
first law) not being an exact differential.