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some small typos in 5
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@ -39,12 +39,14 @@ In thermodynamics the second law tells us that in this setting no
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energy can be extracted indefinitely in a periodic manner. It turns
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out, that in the full quantum case such a result can be obtained by
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studying bounds on the ergotropy of the system as is done in
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\cref{sec:ergo_general}. Remarkably these bounds will turn out to be
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finite. We will review a general bound for single bath systems in
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\cref{sec:ergo_general}. Remarkably, these bounds, originating from
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\refcite{Biswas2022May,Alicki2013Apr,Lobejko2021Feb}, will turn out to
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be finite for finite dimensional systems coupled to infinite baths. We
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will review a general bound for single bath systems in
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\cref{sec:ergoonebath} and study an explicit calculation for a simple
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case in \cref{sec:explicitergo}. The
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explicit ergotropy calculation will elucidate under which conditions
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the bound of \cref{sec:ergoonebath} may be expected to be tight.
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case in \cref{sec:explicitergo}. The explicit ergotropy calculation
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will elucidate under which conditions the bound of
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\cref{sec:ergoonebath} may be expected to be tight.
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The second problem is a generalization of the above considerations to
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systems coupled to multiple baths of different temperature. In this
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@ -91,9 +93,10 @@ as~\cite{Binder2018}
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\end{equation}
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which is the maximal energy that can be extracted from a system
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through cyclic modulation of the Hamiltonian \(H\). A state is called
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passive iff the maximizing \(U\) \cref{eq:ergo_def} is the identity
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passive iff the maximizing \(U\) in \cref{eq:ergo_def} is the identity
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\(\id\). In other words, a state is passive if its energy can not be
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reduced through unitary transformations and its ergotropy vanishes.
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reduced through unitary transformations and thus its ergotropy
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vanishes.
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In \refcite{Niedenzu2018Jan} the ergotropy of the system is employed
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for the definition of heat to derive a tighter second law. The
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@ -110,9 +113,9 @@ condition~\cite{Lenard1978Dec}
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\end{equation}
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where \(n<∞\) is the Hilbert space dimension. This condition is both
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necessary and sufficient. Examples of passive states are the state of
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the micro-canonical ensemble or Gibbs states. Gibbs states are further
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distinguished by additional features described
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in \refcite{Lenard1978Dec}, which can be connected to formulations of the
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the micro-canonical ensemble and also Gibbs states. Gibbs states are
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further distinguished by additional features described in
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\refcite{Lenard1978Dec}, which can be connected to formulations of the
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zeroth and second laws of thermodynamics.
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One of these properties is complete passivity. Completely passive
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@ -156,7 +159,8 @@ appropriate. KMS states only enter the NMQSD/HOPS formalism
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indirectly, as they predict the expression for the spectral density of
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the finite temperature noise in \cref{sec:lin_finite}. Due to the
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formulation of the NMQSD which only relies on bath correlation
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functions, the problem of non-existing states is circumvented.
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functions, the problem of formally non-existing states is
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circumvented.
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In fact, we see in \cref{fig:bcf_approx} that the BCF of an infinite
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bath can be approximated very well by a finite number of evenly spaced
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@ -207,7 +211,7 @@ finite. This amounts to the formulation of the second law: ``No energy
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may be extracted from a single bath in a cyclical manner''. For
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systems obeying weak coupling dynamics, thermodynamic laws can be
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derived in certain situations\footnote{very slow or very fast
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modulation of the system hamiltonian}\cite{Binder2018}, which imply
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modulation of the system hamiltonian}~\cite{Binder2018}, which imply
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the answer ``yes'' for the above questions. In the non-Markovian case
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however, those arguments do not hold anymore.
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@ -215,16 +219,17 @@ For finite dimensional baths, we always have finite ergotropies, as
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their Hamiltonians are bounded. In the infinite dimensional case, we
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may expect that the ergotropy is still finite for some models, as long
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as the energies of the thermal states for those models is finite. This
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assumption breaks down when we consider infinite baths, whose thermal
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energy is unbounded even for finite temperatures. We therefore
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slightly reformulate our problem. The question is now, whether the
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ergotropy can be made arbitrarily large by enlarging the bath. This is
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consistent with approaching the infinite bath case as a limit.
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assumption breaks down when we consider baths consisting of an
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infinite number of subsystems, whose thermal energy is unbounded even
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for finite temperatures. We therefore slightly reformulate our
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problem. The question is now, whether the ergotropy can be made
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arbitrarily large by enlarging the bath. This is consistent with
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approaching the infinite bath case as a limit.
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There is a simple and general argument that provides an upper bound on
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the ergotropy of states of the form~\cref{eq:simple_initial_state}
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based on the special form of Gibbs states and relative entropy. The
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latter quantity allows the application of quantum informational tools,
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latter quantity allows the application of quantum informational tools
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even in the presence of infinite baths if we are careful in taking
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limits.
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@ -677,8 +682,8 @@ energy that can be extracted out of the system in relation to the
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energy that is simply transferred between the baths.
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An argument based on entropy may be made for the periodic steady state
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as was shown in \refcite{Kato2016Dec} and is reproduced here with the
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slight generalization of multiple baths and modulated coupling. We
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as was shown in \refcite{Kato2016Dec} and is reproduced here with a
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slight generalization to multiple baths and modulated coupling. We
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will find a Clausius-like form of the second law. The left-hand side
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of this inequality can then be interpreted as thermodynamic cost of
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the cyclical process.
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@ -790,11 +795,11 @@ motivated in \refcite{Riechers2021Apr}, where heat is identified with
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bath is being considered and brought into connection with
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information-theoretic quantities.
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If one defines heat in this
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way~\cite{Kato2016Dec,Riechers2021Apr,Strasberg2021Aug},
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If one defines heat in this way as is done in
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\refcite{Kato2016Dec,Riechers2021Apr,Strasberg2021Aug},
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\cref{eq:secondlaw_cyclic} amounts to the Clausius inequality. The
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definition of heat as bath energy change is corroborated
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in \refcite{Esposito2015Dec} where it is shown, ableit for fermionic
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definition of heat as bath energy change is corroborated in
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\refcite{Esposito2015Dec} where it is shown, ableit for fermionic
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baths, that a definition of heat involving any nonzero fraction of the
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interaction energy will lead to the internal energy (as defined by the
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first law) not being an exact differential.
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